Mineral wool or polystyrene beads: which cavity fill?
Blown mineral wool is non-combustible and usually a little cheaper; bonded polystyrene bead flows into narrow and uneven cavities more evenly and some bead systems are certified for higher driving-rain exposure. Neither is best everywhere: the wall, its exposure and the building's use decide.

Side by side
| Blown mineral wool | Bonded polystyrene bead | |
|---|---|---|
| What it is | Water-repellent glass or stone fibre | EPS beads coated with a binder |
| Fire | Non-combustible | Combustible; certificate sets limits |
| Narrow or uneven cavities | Less forgiving | Flows around obstructions |
| Exposure | Common in sheltered and moderate zones | Some systems certified for higher exposure |
| Cables in the cavity | No special precautions | PVC cables checked and protected |
| Typical price | A little lower | A little higher |
What about foam?
Old urea-formaldehyde foam is no longer a mainstream choice, and some foam materials need an assessment of formaldehyde emissions under the Building Regulations. Modern polyurethane foam has specialist uses, such as stabilising failing wall ties, rather than general cavity filling.
Related services
Sources: Planning Portal: cavity wall insulation and building regulations; Energy Saving Trust: cavity wall insulation.